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Dibromine pentoxide is the chemical compound composed of bromine and oxygen with the formula Br2O5. It is a colorless solid that is stable below −20 °C. It has the structure O2Br−O−BrO2, the Br−O−Br bond is bent with bond angle 121.2°. Each BrO3 group is pyramidal with the bromine atom at the apex.[2]

Reactions

Dibromine pentoxide can be prepared by reacting a solution of bromine in dichloromethane with ozone at low temperatures and recrystallized from propionitrile.[1][2]

References

  1. ^ a b Perry, Dale L.; Phillips, Sidney L. (1995), Handbook of Inorganic Compounds, CRC Press, p. 74, ISBN 0-8493-8671-3, retrieved 25 August 2015
  2. ^ a b Wiberg, Egon (2001). Wiberg, Nils (ed.). Inorganic chemistry (1st ed.). San Diego, Calif.: Academic Press. p. 464. ISBN 9780123526519.